Atoms and thermal energy

If you use a powerful microscope to observe a tiny speck of pollen floating in water, then you will observe the pollen speck to move constantly in a jerky, irregular way. This motion was first seen by Irish botanist Robert Brown in 1827, and he was mystified by it. It was not until 1905 that Einstein gave the correct interpretation to Brownian motion when he recognized that, on the atomic level, matter is in constant motion. Individual atoms are constantly jostling each other and colliding with each other trillions of times every second. Brownian motion occurs when a particle is so small that the effect of individual collisions with water molecules are evident, even though water molecules themselves are a thousand times smaller.
Motion of particles in the gas phase The microscopic thermal motion of atoms is most easily seen in the motion of particles in a gas. Molecules zoom past each other at high speeds, because the average molecule is extremely energetic. Only a few particles are visible at any given time, because most gases have low density. Gas particles are effectively not bound to each other—each gas particle moves on its own, free from every other particle. But occasionally they do collide!
Motion of particles in the liquid phase At lower temperatures, matter is in its liquid phase. Liquid particles move more slowly past each other than gas particles because they experience weak, intermolecular attractive forces. As these liquid particles get closer to each other, they experience a repulsive force due to the negatively-charged outer electrons of the atoms. As a result, liquid particles can pack together, but only to an extent! They move past each other at slower speeds, because liquid molecules have lower average kinetic energies than gas particles. Show van der Waals forces
Motion of particles in the solid phase Atoms attract other atoms with forces that at first become stronger as two atoms get closer, but then quickly become repulsive when the atoms start to overlap. In a liquid, the thermal energies of the particles is enough to overcome these attractive forces, so the particles can move about each other. In a solid, however, the lower thermal energies of the particles cannot break the attractive force, so the atoms remain in place. But that doesn't mean they don't move! Particles in a solid still have thermal energy that causes them to vibrate. The higher the temperature of the solid, the more energetically the particles are vibrating in place. Show Random kinetic energy
Which common phase of matter has the least intermolecular forces?
  1. Solid
  2. Liquid
  3. Gas
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